✦ LIBER ✦

The thermal decomposition of hydrocarbon copolymers-V Products and mechanism of decomposition of copolymers incorporating styrene

✍ Scribed by J.R. MacCallum; K. Paterson

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 209 KB
Volume: 10
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(74)90195-5

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✦ Synopsis

The products of the thermal decomposition of a series of copolymers of structure

Ph

Ph A with n = 0, I, 3, 4 and 5, have been investigated. A high proportion of the products consists of low molecular weight analogues of the parent polymers, with styrene the major constituent of the volatile liquids. The eopolymers are more stable than head-to-tail polystyrene. Some general conclusions are drawn on the overall mechanism of breakdown.

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