𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The theory of electrochemical instabilities

✍ Scribed by Marc T.M. Koper

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
662 KB
Volume
37
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

✦ Synopsis

A simple and largely general theory is developed for instabilities occurring in electrochemical reactions with a simple negative Faradaic impedance. For the system under fixed circuit potential (ie across cell plus external resistance), the theory predicts the existence of a universal phase diagram which assembles the system's stationary and oscillatory behavior and their associated bifurcations. Under galvanostatic control, these systems are not expected to give rise to oscillations, only multistability.

πŸ“œ SIMILAR VOLUMES

On the Criteria of Instability for Elect
On the Criteria of Instability for Electrochemical Systems
✍ Ze-Lin Li; Bin Ren; Zhen-Jiang Niu; Xiao-Ming Xiao; Yue Zeng; Zhong-Qun Tian πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 491 KB

## Abstract Both cyclic‐voltammetry‐based and impedance‐based experimental criteria that have been developed recently for the oscillatory electrochemical systems are critically appraised with two typical categories of oscillators. Consistent conclusions can be drawn by the two criteria for the cate

On the perturbation theory of instable i
On the perturbation theory of instable isolated eigenvalues
✍ M. Demuth πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 446 KB

## Abstract The problem of the perturbation of an operator having a continuous spectrum and an isolated eigenvalue Ξ»~0~ is considered by means of the theory on embedded eigenvalues. The perturbation is divided up into two parts. One part is used for embedding the isolated eigenvalue Ξ»~0~. This embe