This text focuses on the practical aspects of crystal structure analysis, and provides the necessary conceptual framework for understanding and applying the technique. By choosing an approach that does not put too much emphasis on the mathematics involved, the book gives practical advice on topics s
The Theory of Crystal Structure Analysis
β Scribed by A. I. Kitaigorodskii (auth.)
- Publisher
- Springer US
- Year
- 1961
- Tongue
- English
- Leaves
- 284
- Edition
- 1
- Category
- Library
No coin nor oath required. For personal study only.
β¦ Synopsis
Structure analysis is based on the phenomena of the diffraction of radiaΒ tion by materials. In the first ten to twenty years after Laue's discovery, a very complete theory was developed for the diffraction of x-rays and, later, of electrons. This theory led to equations by means of which it was possible to compute the intensity pattern for a given structure. The theory of structure analysis came to mean that of the diffraction of radiation. In 1935, Patterson pointed out a way leading to the solution of the inverse problem: the finding of the structure from a given intensity distribution pattern. At first the conservatism of researchers, and then the war, hampered the deΒ velopment and broad application of the ideas set forth in this work. It was only during the last ten years that all the rich possibilities of the Patterson method - the method of the analysis of the convolution of the electron density - were brought to light and applied in practice.
β¦ Table of Contents
Front Matter....Pages i-xi
Mathematical Introduction....Pages 1-18
Principles of the Theory....Pages 19-66
Structure Amplitudes and Products as Random Quantities....Pages 67-126
The Theory of the Relations between Structure Amplitudes....Pages 127-205
Analysis of the Convolution of the Electron Density....Pages 206-241
Methods of Obtaining Agreement between the Measured and Calculated Structure Amplitudes....Pages 242-269
Conclusion....Pages 270-272
Back Matter....Pages 273-275
β¦ Subjects
Crystallography
π SIMILAR VOLUMES
This concise book is for chemists, material scientists, and physicists who deal with description of crystalline matter and the determination of its structure, and would like to gain more understanding of the principles involved. The main purpose of the book is to introduce the reader to principles o
Crystal Structure Analysis, Third Edition, explains how and why the detailed three-dimensional architecture of molecules can be determined by an analysis of the diffraction patterns obtained when X-rays or neutrons are scattered by the atoms in single crystals. Part 1 covers the nature of the crysta