✦ LIBER ✦
The theoretical description of an asymmetric, nonresonant charge transfer process; Li + Na+ ⇌ Li+ + Na the two-state approximation
✍ Scribed by Carl F. Melius; William A. Goddard III
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 401 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The charge transfer process for the collision Li + Na ÷ ~ Li ÷ + Na has been studied theoretically by a two-state, impact parameter approach using molecular wavefunctions. Including the coupling term (4 lla/aRI¢,2> due to the breakdown of the Born-Oppenheimer approximation,we obtain total charge transfer cross sections in good agreement with experimental results.