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The tetrahydropyranyl group as a chiral auxiliary for the nucleophilic addition to α-alkoxy ketones

✍ Scribed by André B. Charette; Abdel F. Benslimane; Christophe Mellon


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
239 KB
Volume
36
Category
Article
ISSN
0040-4039

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✍ Herbert C. Brown; Guang-Ming Chen; P. Veeraraghavan Ramachandran 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 125 KB 👁 1 views

Several new chiral auxiliaries with differing steric and electronic environments, such as ␣,␣Ј-dimethyl-2,6-pyridinedimethanol, ␣,␣Ј-ditrifluoromethyl-2,6pyridinedimethanol, ␣,␣Ј-dipentafluoroethyl-2,6-pyridinedimethanol, and ␣,␣Ј-diallyl-2,6pyridinedimethanol, have been examined and compared with ␣