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The temporary silicon connection method in the control of regio- and stereochemistry. Applications to radical-mediated reactions. The stereospecific synthesis of C-glycosides

✍ Scribed by Stork, Gilbert; Suh, Hong Suk; Kim, Guncheol


Book ID
126034737
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
388 KB
Volume
113
Category
Article
ISSN
0002-7863

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A stereoselective method for introducing a C2-unit at the 1 or-and 1 I~-postions of D-glucose and D-mannose, respectively, via a radical cyclization reaction with vinylsilyl group as a temporary connecting tether, was developed. The radical cyclization of D-glucose substrates was effectively facilit