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The tautomerism of 1,2,3-triazole in aqueous solution

✍ Scribed by Albert, Adrien; Taylor, Peter J.


Book ID
119953890
Publisher
Royal Society of Chemistry
Year
1989
Tongue
English
Weight
301 KB
Volume
11
Category
Article
ISSN
1472-779X

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The tautomerism of 1,2,3-triazole, 3(5)-
✍ Javier CatalΓ‘n; Marta SΓ‘nchez-Cabezudo; JosΓ© Luis G. De Paz; JosΓ© Elguero; Rober πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 English βš– 656 KB

The annular tautomerism of 1,2,3-triazole and 3(5)-methylpyrazole is discussed by means of a combination of theoretical calculations and experimental (ICR) gas-phase basicities and acidities. In the gas phase 1,2,3-triazole exists as the ZH-tautomer, whereas both tautomers of 3(5)-methylpyrazole are