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The synthesis, structure and infrared spectra of pyridinium bromochromate

✍ Scribed by S. Durai; V. Ravikumar; N. Narayanan; T.R. Balasubramanian; S. Mohan

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
120 KB
Volume
43
Category
Article
ISSN
1386-1425

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The kinetics of oxidation of four vicinal diols, four nonvicinal diols, and one of their monoethers by pyridinium bromochromate (PBC) have been studied in dimethyl sulfoxide. The main product of oxidation is the corresponding hydroxyaldehyde. The reaction is first-order with respect to each the diol

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## Abstract The oxidative deoximination of several aldo‐ and keto‐oximes by pyridinium bromochromate (PBC), in dimethylsulfoxide, exhibited a first‐order dependence on both the reductant (oxime) and the oxidant (PBC). The oxidation of ketoximes is slower than that of aldoximes. The rates of oxidati