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The synthesis ofrac-peniolactol and some related compounds

✍ Scribed by Rama, Nasim H. ;Saeed, Aamer ;Bird, Clive W.

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
348 KB
Volume
1995
Category
Article
ISSN
0947-3440

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✦ Synopsis

Isocoumarins I Ring-chain tautomerism I Peniophora sanguinea

The structure (?)-3,6,8-trihydroxy-3-pentadecyl-3,4-dihy-by total synthesis of this compound and some of its derivatidroisocoumarin 1 assigned by earlier workers to peniolactol, a metabolite of Peniophora sunguinea, has been confirmed ves.

Peniolactol is a metabolite of the wood attacking fungus Penio- phoru sunguinea Bres. A notable feature of the structure 1 as-

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