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The Synthesis of β-Oxoesters from Acyl Pyruvates

✍ Scribed by Dessert, Alice M.; Halverstadt, I. F.

Book ID
120157033
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
148 KB
Volume
70
Category
Article
ISSN
0002-7863

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An efficient and highly flexible synthes
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✍ Ingrid Böhm; Rick Schulz; Hans-Ulrich Reissig 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 213 KB

Slloxy substituted methyl cyclopropanecarboxylates are cleaved by bromine to afford \*-bromo-r-oxoester and, after treatment with tnethylamine, good yields of ol,bunsaturated r-oxoesters Many macrollde antibiotics incorporate the roxocrotonate block l-3 . In addition, the more general type of e,R-un