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The synthesis of α,α-difluoroaldehydes and ketones via claisen rearrangements

✍ Scribed by Brian W. Metcalf; Esa T. Jarvi; Joseph P. Burkhart

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
213 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis

The Claisen rearrangements of reactants the ally1 or vinyl fragment are described.

📜 SIMILAR VOLUMES

Synthesis of α-C-glycosides via tandem T
Synthesis of α-C-glycosides via tandem Tebbe methylenation and Claisen rearrangement
✍ H.Yasmin Godage; Antony J. Fairbanks 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 264 KB

A variety of a-C-glycosides may be accessed in an entirely stereoselective fashion from 3-OH glycal esters, by way of the tandem reaction sequence of Tebbe methylenation and Claisen rearrangement. In contrast with previous studies in the corresponding b-series, careful control of conditions for Clai