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The Synthesis of the First Compound with Li-Si-Hg Bonding: [{Li(iPr3Si)2Si}2Hg]—a Source for the [Li(iPr3Si)2Si]. Radical

✍ Scribed by Dmitry Bravo-Zhivotovskii; Michael Yuzefovich; Nadejda Sigal; Gady Korogodsky; Karl Klinkhammer; Boris Tumanskii; Alex Shames; Yitzhak Apeloig


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
95 KB
Volume
41
Category
Article
ISSN
0044-8249

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Synthesis and Crystal Structure of the t
✍ Karl Wilhelm Klinkhammer 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 153 KB 👁 2 views

The two hypersilylcuprates LiCu 2 Hyp 3 (2) and [Li 7 (O t Bu) 6 ][Cu 2 Hyp 3 ] (3) (Hyp = Si(SiMe 3 ) 3 ) were synthesized by reactions of unsolvated lithium hypersilanide, Li-Hyp with hypersilylcopper and CuO t Bu, respectively. Both contain the novel A-frame trihypersilyldicuprate anion [Cu 2- Hy