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The synthesis of some cholest-7-en-6-one derivatives related to ecdysones

✍ Scribed by K.T. Alston; P.M. Bebbington; Susan E. Green; E.D. Morgan; C.F. Poole


Book ID
119481372
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
350 KB
Volume
27
Category
Article
ISSN
0039-128X

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The X-ray crystal structure of 3~-benzoyloxy-6a-chloro-5a-cholest-7-ene (IV) was determined by the heavy atom method and ref'med to R ---0.063 (space group P2s, a --11.364, b = 11.089, c --12.232,/~ = 99.43 Β°, Z ---2). IV was previously shown to be an important intermediate in the acid-catalyzed iso