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The synthesis of some 2,10-epoxypinanes

โœ Scribed by J.M. Coxon; E. Dansted; M.P. Hartshorn; K.E. Richards


Book ID
103397451
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
341 KB
Volume
24
Category
Article
ISSN
0040-4020

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Synthesis and reactions of dipyrromethan
โœ Antonio Garrido Montalban; Antonio J. Herrera; Jes Johannsen; Josephine Beck; Th ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 78 KB

Dipyrromethane-2,10-dicarboxylates have been prepared. While oxidation and subsequent reaction of 5b with BF 3 โ€ขOEt 2 yields the corresponding complex 10, ring-closing metathesis of 5d using (NHC)(PCy 3 )(Cl) 2 Ru CHPh 7 results in the novel hybrid macrocycle 8. The structure of 10 has been unequivo