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The Synthesis of Solvent-Free Glycidic Esters from Diazoesters and Carbonyl Compounds Catalysed by Lanthanide Triflates

✍ Scribed by Massimo Curini; Francesco Epifano; Maria Carla Marcotullio; Ornelio Rosati

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 200 KB
Volume: 2002
Category: Article
ISSN: 1434-193X
DOI: 10.1002/1099-0690(200205)2002:9<1562::aid-ejoc1562>3.0.co;2-q

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✦ Synopsis

The results of the reaction between ethyl diazoacetate and carbonyl compounds catalysed by lanthanide triflates are described. Aldehydes, and α-unsubstituted and α-monosubstituted cyclohexanones react to give the selective formation [a

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