The synthesis of poly(phenylacetylene)s with bulky chiral silyl groups and the thermal stability of their helical conformation

Synthesis of poly(silyl ether)s containi

Synthesis of poly(silyl ether)s containing pendant chloromethyl groups by the polyaddition of bis(oxetane)s with dichlorosilanes

✍ Shouji Minegishi; Muneharu Ito; Atsushi Kameyama; Tadatomi Nishikubo 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 110 KB 👁 2 views

The polyaddition of bis(3-ethyl-3-oxetanylmethyl) terephthalate (BEOT) with dichlorodiphenylsilane (CPS) using tetrabutylammonium bromide (TBAB) as a catalyst proceeded under mild reaction conditions to afford a polymer containing silicon atoms in the polymer main chain. A poly(silyl ether) (P-1) wi