The synthesis of new electron-deficient naphthoquinones
✍ Scribed by Matthew W. Forkner; Reuben D. Rieke
- Book ID
- 116137026
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 485 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0379-6779
No coin nor oath required. For personal study only.
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## Abstract Two new, covalently‐linked pyropheophytin‐naphthoquinone dyads 1 and 2 have been synthesized for use as model compounds in studies of photoinduced electron transfer. The starting material for the synthesis was chlorophyll __a__ (3). This was first pyrolyzed to 13^2^‐demethoxycarbonylchl
## Abstract The reaction of 1,4‐naphthoquinone (1) with __N__‐alkylpyrroles (2) gives a mixture of 2‐(pyrrol‐2‐yl)‐1,4‐naphthoquinones (3) and 2,5‐bis(1,4‐naphthoquinon‐2‐yl)pyrroles (4). The yields and the ratios of these two products depend greatly on the experimental conditions. The reaction has