✦ LIBER ✦

The synthesis of neosporol: A trichothecene in search of a natural product

✍ Scribed by Frederick E. Ziegler; Ashwini Nangia; Gayle Schulte

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 217 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)82013-4

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✦ Synopsis

The synthesis of neosporol 14, a yet to be discovered trichothecene, is described. The critical reaction is a highly diastereoselective Claisen rearrangement that sets the Cs -C 6 stereochemistry.

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