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The Synthesis of Isomeric Unsymmetrical Benzoins

✍ Scribed by Jenkins, Sanford S.


Book ID
127077425
Publisher
American Chemical Society
Year
1933
Tongue
English
Weight
70 KB
Volume
55
Category
Article
ISSN
0002-7863

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Preparation and properties of unsymmetri
✍ John E.T. Corrie πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 563 KB

Synthesis of unsymmetrical benzoins and their esters can be compromised by isomerisation via the enediol (or its anion). This could be avoided by suitable reaction conditions for the benzoins and their esters 2a/b and 3a/b but not for the 3-furyl compound 4a. A convenient synthesis of 3,5dimethoxy-2