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The synthesis of highly pure octachlorocyclotetraphosphazene (PNCl2)4+

✍ Scribed by Kouřil, Milan; Mezník, Lubomír; Dlabaja, Ladislav


Book ID
118259121
Publisher
UOCHB
Year
1988
Tongue
English
Weight
209 KB
Volume
53
Category
Article
ISSN
0010-0765

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Addition of molecular fluorine to cis-2-cyclopentene-1 ,Cdiol gave the c&anti adduct stereoselectively. This meso diol was dissymmetrized by means of acetylation under lipase catalysis to afford the monoacetate with a high enatiomeric purity. Oxidation of the monoacetate followed by elimination of h