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The synthesis of functionalised silyltriflates

โœ Scribed by Alan R. Bassindale*; Tim Stout


Book ID
103225393
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
185 KB
Volume
271
Category
Article
ISSN
0022-328X

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Synthesis of a functionalised bis-spiroa
โœ Margaret A Brimble; Geoffrey M Williams; Raymond Baker; Mark James ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 234 KB

The synthesis of bis-spiroacetal (15) bearing an hydroxymethyl group at c-2 is described establishing a methodology for preparation of the polyether antibiotics salinomycin and narasin. Formation of an important iodohydrin intermediate has been accomplished by a highly efficient reaction of an epox