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The Synthesis of Cyclic Enol Ethers via Molybdenum Alkylidene-Catalyzed Ring-Closing Metathesis

✍ Scribed by Fujimura, Osamu; Fu, Gregory C.; Grubbs, Robert H.


Book ID
120206426
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
273 KB
Volume
59
Category
Article
ISSN
0022-3263

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Highly regioselective synthesis of cycli
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We developed the first highly regioselective synthesis of cyclic enol ethers from readily accessible acyclic alkenyl ketones or acyclic alkenyl silyl esters using ring-closing metathesis (RCM). The RCM of acyclic enol silyl ethers was examined using Tebbe reagent 5 or Grubbs catalyst 6 or 7 and succ