The synthesis of barbaralyl systems via bicyclic[3.2.2] irontricarbonyl cations
โ Scribed by S. Abramson; A. Eisenstadt
- Book ID
- 103396586
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 834 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4020
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Synthetic approaches for the preparation of oxygenated bicycle (2.2.2) octanes,3 include among others, 1 the use of 4+2 cycloaddition reactions of both dienolates2 and their acetoxy derivatives,s3 The former method suffers from the fact that the reaction conditions are strongly basic, while the latt
## Abstract New bicyclic 2โmethyleneโ1,3โdioxepanes, were synthesized starting from 2โbromomethylโ5,6โdihydroxyโ1,3โdioxepanes. The structure of the 2โmethyleneโ1,3โdioxepanes was confirmed by elemental analysis, IR, ^1^H NMR and ^13^C NMR spectroscopy. Radical polymerization of 2โmethyleneโ1,3โdio