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The synthesis of a natural product family: from debromoisolaurinterol to the aplysins

โœ Scribed by David C Harrowven; Matthew C Lucas; Peter D Howes

Book ID
108371061
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
261 KB
Volume
57
Category
Article
ISSN
0040-4020

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A diastereoselective radical to polar cr
A diastereoselective radical to polar crossover sequence for the synthesis of the isolaurinterols and aplysins
โœ David C. Harrowven; Matthew C. Lucas; Peter D. Howes ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 152 KB

Total syntheses of aplysin 1. debromoaplysin 2, aplysinol 3. debromoaplysinol 4, isoaplysin 5. isolaurinterol 6 and debromoisolaurinterol 7 am described. Key features am a diastereoselective radical to pol ar crossover sequence to transform di ne 8 into debromoisolaurinterol 7 and a series of biomim