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The synthesis of a mannosyl-N-acetylglucosamine-l-asparagine compound: 2-acetamido-N-(l-aspart-4-oyl)-2-deoxy-3-O-α-d-mannopyranosyl-β-d-glucopyranosylamine

✍ Scribed by Mohammed A.E. Shaban; Roger W. Jeanloz

Book ID
108308655
Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
848 KB
Volume
21
Category
Article
ISSN
0008-6215

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📜 SIMILAR VOLUMES

The synthesis of disaccharide-L-asparagi
The synthesis of disaccharide-L-asparagine compounds: derivatives of N-(L-aspart-4-oyl)-4-O-β-D-galactopyranosyl-β-D-glucopyranosylamine (lactosyl-L-asparagine), 2-acetamido-N-(L-aspart-4-oyl)-2-deoxy-4-O-β-D-galactopyranosyl-β-D-glucopyranosylamine (N-acetyllactosaminyl-L-asparagine), and 2-acetamido-N-(L-aspart-4-oyl)-2-deoxy-6-O-β-D-galactopyranosyl-β-D-glucopyranosylamine
✍ Massimiliano Spinola; Roger W. Jeanloz 📂 Article 📅 1970 🏛 Elsevier Science 🌐 English ⚖ 722 KB
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✍ Brad Bendiak; Dale A. Cumming 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 729 KB

2-Acetamido-1-N-(L-aspart-4-oyl)-2-deoxy-beta-D-glucopyranosyla mine (1) was used as a model glycopeptide to study the hydrazinolysis-N-reacetylation procedure. The major, initial product was the beta-acetohydrazide derivative of 2-acetamido-2-deoxy-D-glucose (2) which gave 2-acetamido-2-deoxy-D-glu