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The Synthesis of 5-Allyluracil and the Pyrimidine Claisen Rearrangement 1

โœ Scribed by MINNEMEYER, HARRY J.; EGGER, JOHN A.; HOLLAND, JAMES F.; TIECKELMANN, HOWARD


Book ID
126259722
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
675 KB
Volume
26
Category
Article
ISSN
0022-3263

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Synthesis and claisen rearrangement of 1
โœ M.J. Sleeman; G.V. Meehan ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 281 KB

A number of ally1 allenyl ethers (1) have been synthesised and shown to undergo the Claisen rearrangement. The kinetics of rearrangement of (lb) together with stereochemical data obtained, is consistent with a concerted mechanism for these rearrangements. A number of variants of the Claisen rearra