The synthesis of 4-substituted-4H-1,2,4-triazole-3-thiols and 3-methylthio-4-substituted-4H,2,4-triazoles
β Scribed by Yang-i Lin; S. R. Petty; F. M. Lovell; N. A. Perkinson; S. A. Lang Jr.
- Book ID
- 112126105
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1980
- Tongue
- English
- Weight
- 236 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0022-152X
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π SIMILAR VOLUMES
## By means of regioselective S-alkylation of 1H-1,2,4-triazole-3-thiol (1), a series of S-substituted derivatives 2a-j were synthesized. In certain conditions, the reaction of 2 with arylsulfochlorides, arylisocyanates, and quaternary ammonium salts of azines corresponding compounds were obtained
In the title compound, C 12 H 12 N 6 O 2 S, the thiophene ring is disordered equally over two positions, corresponding to rotation of approximately 180 about the C-C single bond. The central triazole ring has substituents at the 1-, 3-, 4-and 5positions. Intermolecular C-HΓ Γ ΓN and C-HΓ Γ ΓO intera