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The synthesis of 4-deoxy-L-glycero-pentulose by biochemical dehydrogenation of 2-deoxy-D-erythro-pentitol

✍ Scribed by Kazimír Linek; Rozália Sandtnerová; Tibor Sticzay; Vladimír Kovác̆ik; Milos̆ Kulhánek; Milan Tadra

Book ID
102639327
Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
367 KB
Volume
76
Category
Article
ISSN
0008-6215

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A study aimed at developing an enantioselective synthesis of the title compound 23, a 2-monodeoxy analogue of the naturally occurring ()-2-keto-3-deoxy-d-glycero-d-galacto-2-nononic acid (KDN), is reported. From d-mannose as starting material, the chiral 1,3-diene 10, activated by a silyloxy substit