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THE SYNTHESIS OF 3-R-7-CARBOMETHOXYMETHYLENE-7H-1,2,4-TRIAZOLO[3,4-b]-1,3,4-THIADIAZIN-6-ONES

โœ Scribed by Heindel, Ned D.; Reid, Jack R.


Book ID
120650634
Publisher
Taylor and Francis Group
Year
1981
Tongue
English
Weight
155 KB
Volume
13
Category
Article
ISSN
0030-4948

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The reaction of 3-mercapto-4-aryIideneamino-l,2,4triazoles 2b-d, 3a-d with ethyl bromoacetate and/or phenacyl bromide in hot DMF and triethylamine affords the stereochemically pure 7-acyl-6-aryl-6,7dihydro-5H-lt2, 4-triazolo[3,4-b][l, 3,4]thiadiazines