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The synthesis of 1H-, 3H-, and 5H-2-benzazepine derivatives in the reaction of bicyclic aromatic nitro compounds with dimethyl phosphite and amines in the basic conditions

✍ Scribed by Danikiewicz, Witold; Makosza, Mieczyslaw


Book ID
126177270
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
536 KB
Volume
56
Category
Article
ISSN
0022-3263

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Synthesis of aromatic amine phosphonato
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## Abstract Aromatic amine phosphonato esters **4a–d** were obtained in excellent yields from the 1:1:1 addition reaction between triphenyl phosphite and dimethyl acetylenedicarboxylate in the presence of NH‐aromatic amines such as 2‐aminobenzophenone, 2‐aminoacetophenon, methyl‐2‐aminobenzoate, an