The synthesis of 1,4-diazacycl[3,2,2]azine
โ Scribed by William W. Paudler; Richard A. Vandahm; Young N. Park
- Book ID
- 112122582
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1972
- Tongue
- English
- Weight
- 341 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0022-152X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
We wish.to report reactions leading to a new heterocyclic system of 1,4-diazacyc1[3.2.2]azine (I). We use the nomenclature proposed by V. Boekelheide in his definitive paper on cyclazines (1). 5-Amino-2-methylimidazo[l,l-alpyridine (2) was acetylated with acetic anhydride. The..reaction mixture was
Novel 5-thia-1-azacycl[3.3.2]azine derivatives 1, 5-thia-1,8b-diazaacenaphthylenes, have successfully been prepared. An X-ray crystallographic analysis of 1c revealed that the 5-thia-1-azacycl[3.3.2]azine ring system adopts a planar structure as to the internal ring nitrogen atom. The 1 H NMR spectr