## Abstract The 3,6‐substituted 1,2,4‐trioxan‐5‐ones 11–14, on heating to 170–200°, underwent unimolecular thermolysis to generate electronically excited singlet ketones with an efficiency of __ca.__ 0.2%. The chemiluminescence quantum yields (ϕoS~CL~) depended on the nature of the 6‐substitutents
The Synthesis of 1,2,4-Trioxan-5-ones
✍ Scribed by Charles W. Jefford; Jane Currie; Geoffrey D. Richardson; Jean-Claude Rossier
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- German
- Weight
- 547 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
Several 3,6‐substituted 1,2,4‐trioxan‐5‐ones have been prepared in good yield by condensing aldehydes and ketones with trimethylsilyl α‐[(trimethylsilyl)peroxy]alkanoates in the presence of trimethylsilyl trifluoromethane sulfonate as catalyst.
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## Abstract magnified image A new method for the synthesis of substituted 5‐(2‐hydroxyethyl)‐2‐phenylimino‐1,3‐thiazolidin‐4‐ones and 5‐(2‐hydroxyethyl)‐2‐phenylamino‐4,5‐dihydro‐1,3‐thiazol‐4‐ones is described, starting from phenylthioureas and 3‐bromotetrahydrofuran‐2‐one. The reaction proceeds
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