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The synthesis and the structure elucidation of N,O-diacetyl derivative of cyclic 3-hydroxymelatonin

✍ Scribed by Siwicka, Aleksandra ;Reiter, Russel ;Tian, Dun ;Wojtasiewicz, Krystyna ;Leniewski, Andrezej ;Maurin, Jan ;Błachut, Dariusz ;Czarnocki, Zbigniew


Book ID
111487732
Publisher
Walter de Gruyter GmbH
Year
2004
Tongue
English
Weight
495 KB
Volume
2
Category
Article
ISSN
2391-5420

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✍ Pier Luigi Barili; Giorgio Catelani; Fabrizia Colonna; Alberto Marra; Silvio Cer 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 821 KB

Kinetically controlled reaction of 4.5 equiv. of 2-methoxypropene with some alkyl (Y-and /3-o-galactopyranosides gave the 2,3:4,6-di-O-isopropylidene derivatives in high yields @O--85%). With 2 equiv. of 2-methoxypropene, benzyl P-Dgalactopyranoside gave the 4,6-and the 3,4-monoacetals in the ratio