The Synthesis and Structure of P−C−P Bridged Ferrocene
✍ Scribed by Igor Shevchenko; Dmitrii Shakhnin; Hongming Zhang; Michael Lattman; Gerd-Volker Röschenthaler
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 140 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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Subject classification: 61.46.+w; 73.22.-f; S5 Full-potential linear-muffin-tin-orbital molecular-dynamics (FP-LMTO MD) calculations have been performed to investigate the structures and energies of P 8 and P 9 clusters. We get fourteen stable structures for P 8 and fifteen stable structures for P 9
The totally regio-and stereoselective P-O-to-P-C exception was found with naphthyl derivatives, which gave mixtures of two regioisomers. In all cases, the products rearrangement in the synthesis of various chiral P-(ohydroxyaryl)diaza-phospholidine P-oxides has been generated have been unambiguously