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The synthesis and structural characterization of carborane oligomers connected by carbon-carbon and carbon-boron bonds between icosahedra

✍ Scribed by Xiaoguang Yang; Wei Jiang; Carolyn B. Knobler; Mark D. Mortimer; M.Frederick Hawthorne


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
730 KB
Volume
240
Category
Article
ISSN
0020-1693

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Asymmetric synthesis of α-substituted am
✍ Kolb, Michael ;Barth, Jacqueline 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 1015 KB

## Abstract The asymmetric synthesis of α‐substituted α‐amino acids and propargylamines is described. As chiral auxiliary we used (__S__)‐(–)‐1‐dimethoxymethyl‐2‐methoxymethylpyrrolidine (SDMP, **1**). Treatment of the amino acids or amines with SDMP **1** afforded the corresponding amidines **C**,