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The Synthesis and Some Reactions of Di-t-butylacetic Acid and Di-t-butylketene 1

โœ Scribed by Newman, Melvin S.; Arkell, Alfred; Fukunaga, Tadamichi


Book ID
118183688
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
557 KB
Volume
82
Category
Article
ISSN
0002-7863

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Synthesis and reactions of 3,4-di-t-buty
โœ Juzo Nakayama; Shoji Yamaoka; Masamatsu Hoshino ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 235 KB

Di-g-butylthiophene (1) was surprisingly easily synthesized from readily accessible bis(Z-t-butyl-2-oxoethyl) sulfide (2). Reactions of 1 with a variety of electrophiles were examined. Sterically overcrowded 3,4-di-t-butylthiophene (1) was first synthesized in 19801 after numerous unsuccessful att