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The synthesis and resolution of (±)-1,4-diO-benzyl-2,3-O-isopropylidene-myo-inositol

✍ Scribed by Trupti Desai; Jill Gigg; Roy Gigg; Eloísa Martín-Zamora; Nathalie Schnetz

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
700 KB
Volume
258
Category
Article
ISSN
0008-6215

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✦ Synopsis

An improved procedure for the preparation of 1,2-O-isopropylidene-nqVo-inositol is described. Racemic 1,4-di-O-benzyl-2,3-O-isopropylidene-myo-inositol was prepared by tinmediated benzylation of 1,2-0-isopropylidene-myo-inositol and resolved readily by crystalk sation of the o-camphanates. The use of the chiral 1,4-di-O-benzyl-2,3-O-isopropylidenemyo-inositols as intermediates for the preparation of other chiral derivatives of myo-inositol was investigated. ' Corresponding author. * For a preliminary communication, see ref 1.

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