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The synthesis and properties of some polyfluoroalkoxy substituted phthalocyanines

✍ Scribed by N. V. Kondratenko; V. N. Nemykin; E. A. Lukyanets; N. A. Kostromina; S. V. Volkov; L. M. Yagupolskii

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
83 KB
Volume
01
Category
Article
ISSN
1088-4246

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✦ Synopsis

A series of 4-(polyfluoroalkoxy)phthalonitriles have been prepared in high yield by nucleophilic substitution of the nitro group in 4-nitrophthalonitrile on polyfluoroalkoxy groups at room temperature. These dinitriles have been cyclotetramerized in the presence of cobalt or copper salts into the corresponding phthalocyanine complexes. The spectral properties and coordination chemistry of some of them have been studied.

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