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The synthesis and osmylation of 7,8-dideoxy-1,2:3,4-di-O-isopropylidene-β-l-glycero-d-galacto-oct-7-enopyranose and related studies

✍ Scribed by John S. Brimacombe; Abul K.M.S. Kabir

Book ID
107725779
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
637 KB
Volume
174
Category
Article
ISSN
0008-6215

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X-ray and conformational investigation o
X-ray and conformational investigation of 6-deoxy-7-C-(2-furyl)-1,2:3,4-di-O-isopropylidene-l-glycero-a-d-galacto- heptopyranose
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The crystals of the title compound arc orthorhombic, space group P2,2,2, (Z = 4) with cell dimensions a = 9.791(l), b = 10.235(l), c = 17.703(2) A. The pyranoid ring has a hybrid twist + screw ("T2+"S5) conformation, and the configuration at C-7 is (R).

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✍ Pastora Borrachero; María Jesús Diánez; María Dolores Estrada; Manuel Gómez-Guil 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 71 KB

The publisher regrets that Scheme 1 was omitted from the above Paper. (1) Scheme 1 on page 86 of the above Paper should be changed to the following: (2) The formulae at the top of page 90 should be numbered 25 and 26, respectively.