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The Synthesis and Isolation of a Metal-Substituted Bis-silene

โœ Scribed by Dmitry Bravo-Zhivotovskii; Roman Dobrovetsky; Dmitry Nemirovsky; Victoria Molev; Michael Bendikov; Gregory Molev; Mark Botoshansky; Yitzhak Apeloig


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
358 KB
Volume
120
Category
Article
ISSN
0044-8249

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โœ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 141 KB ๐Ÿ‘ 2 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and โˆ’30ยฐC to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60ยฐC and under 60atm pre