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The Synthesis and Crystal Structures of Two New Hydrated Sodium Monofluorophosphates: NaHPO3F·2.5 H2O (I) and Na2PO3F·10 H2O (II)

✍ Scribed by Hillary A. Prescott; Sergei I. Troyanov; Erhard Kemnitz


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
202 KB
Volume
156
Category
Article
ISSN
0022-4596

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✦ Synopsis


The structures of two new sodium salts of mono6uorophosphoric acid, NaHPO 3 F ' 2.5 H 2 O (I) and Na 2 PO 3 F ' 10H 2 O (II), were determined with single-crystal X-ray di4raction at 160 K. I is monoclinic with the space group C2/c, a ‫؍‬ 19.112(4),


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Hydrothermal Synthesis and Crystal Struc
✍ Jin-Xiao Mi; Ya-Xi Huang; Shao-Yu Mao; Xiao-Dan Huang; Zan-Bin Wei; Zhong-Le Hua 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 352 KB

A sodium indium hydrogen phosphate hydrate, Na 2 In 2 [PO 3 (OH)] 4 ' H 2 O, was synthesized under mild hydrothermal conditions, and the crystal structure was characterized by the singlecrystal X-ray di4raction method. The structure is of a new type with the following data: