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The Synthesis and Crystal Structures of Two-Dimensional Coordination Polymers of Ph 2 P(O)−CH 2 CH 2 −P(O)Ph 2 and Ph 2 P(O)−C 5 H 3 N−P(O)Ph 2 with Praseodymium

✍ Scribed by Spichal, Zdenek; Necas, Marek; Pinkas, Jiri; Novosad, Josef


Book ID
126879409
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
90 KB
Volume
43
Category
Article
ISSN
0020-1669

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Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac