The Synthesis and Characterization of an Aluminophosphate with Chiral Layers;trans-Co(dien)2·Al3P4O16·3H2O
✍ Scribed by David A. Bruce; Angus P. Wilkinson; Mark G. White; J.Aaron Bertrand
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 389 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0022-4596
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A new layered aluminophosphate [C 6 H 21 N 4 ][Al 3 P 4 O 16 ] has been synthesized solvothermally by using triethylenetetramine (tetam) as the structure-directing agent and ethylene glycol as the solvent. The structure of the compound was solved by singlecrystal X-ray di4raction analysis. [C 6 H 21
A chabazite-type cobaltoaminophosphate containing mixedvalence Co atoms with the encapsulated cobalt complex Co 3 Al 3 (PO 4 ) 6 Co(DETA) 2 ' 3(H 2 O) (DETA, diethyltriamine) has been hydrothermally synthesized and structurally determined. The compound with a chabazite structure crystallizes in the