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The synthesis and characterization of a platina(IV)cyclopentane complex

✍ Scribed by Shahram Tangestaninejad; Mehdi Rashidi; Richard J. Puddephatt

Book ID
107811979
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
355 KB
Volume
412
Category
Article
ISSN
0022-328X

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The platina-b-diketones [Pt 2 {(COR) 2 H} 2 (l-Cl) 2 ] (1, R = Me a, Et b) react with phosphines L in a molar ratio of 1 : 4 through cleavage of acetaldehyde to give acylplatinum(II) complexes trans-[Pt(COR)Cl(L) 2 ] (2) (R/L = Me/P(p-FC 6 H 4 ) 3 a, Me/P(p-CH 2 =CHC 6 H 4 )Ph 2 b, Me/P(n-Bu) 3 c, E