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The synthesis and characterisation of two mononuclear tungsten pentacarbonyl complexes of 4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane

✍ Scribed by Annette Nel; James Chapman; Nicholas Long; Gabriel Kolawole; Majid Motevalli; Paul O'Brien


Book ID
108427938
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
146 KB
Volume
19
Category
Article
ISSN
0277-5387

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✍ Claire E Williams; Roy B Lowry; Jim Braven; Simon T Belt 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 134 KB

The synthesis of the ligand 4-methyl-4%-vinyl-2,2%-bipyridine is discussed. Methods previously reported presented problems in terms of yield and purity of a precursor. Traces of starting material (4,4%-dimethyl-2,2%-bipyridine) contaminated the product and this contaminant carried through to the syn