✦ LIBER ✦

The Syntheses and Structures of the Complex Oxide Carbonates Ba11Pd11O20(CO3)2and Ba88Ni87O156(CO3)19)

✍ Scribed by R.J. Crooks; M.T. Weller

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 660 KB
Volume: 128
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.1996.7191

No coin nor oath required. For personal study only.

✦ Synopsis

A new palladate analog, Ba 11 Pd 11 O 20 (CO 3 ) 2 , of the complex copper oxide carbonate, Ba 44 Cu 48 (CO 3 ) 6 O 87.9 , has been synthesized by reaction of PdO and BaCO 3 at 810°C. The structure of this phase and the isostructural nickelate have been refined from high resolution powder neutron diffraction data. The structure consists of cages M 18 O 24 and M 6 O 12 rings (M ‫؍‬ Pd, Ni) separated by barium ions and carbonate groups. A section of the structure separating two M 18 O 24 units is strongly disordered and has been refined as containing either carbonate groups or isolated MO 4 square planes. The presence and symmetry of the carbonate groups in these structures has been investigated by infrared and Raman spectroscopy.

📜 SIMILAR VOLUMES

The Crystal Structure of Ba3CuRu2O9 and

The Crystal Structure of Ba3CuRu2O9 and Comparison to Ba3MRu2O9 (M=In, Co, Ni, and Fe)

✍ J.T. Rijssenbeek; Q. Huang; R.W. Erwin; H.W. Zandbergen; R.J. Cava 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 462 KB

The crystal structure of Ba 3 CuRu 2 O 9 , determined by powder neutron di4raction, is reported for temperatures of 18+295 K. Structural re5nements by powder neutron di4raction for the previously reported compounds Ba 3 M Ru 2 O 9 for M ‫؍‬ Fe, Co, Ni, and In are also reported. All structures consis

Ba44Cu48(CO3)6O87.9: The Structure of “B

Ba44Cu48(CO3)6O87.9: The Structure of “BaCuO2” from Simultaneous X-ray and Neutron Powder Diffraction

✍ Dr. Miguel A. G. Aranda; Dr. J. Paul Attfield 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 411 KB 👁 1 views

Cation-Directed Synthesis of Tungstosili

Cation-Directed Synthesis of Tungstosilicates. Part 1. Syntheses and Structures of K10A-α- [SiW9O34]×24H2O, of the Sandwich-Type Complex K10.75[Co(H2O)6]0.5 [Co(H2O)4Cl]0.25A-α- [K2{Co(H2O)2}3 (SiW9O34)2]×32H2O and of Cs15 [K(SiW11O39)2]×39H2O.

✍ Nathalie Laronze; Jerome Marrot; Gilbert Herve 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 103 KB 👁 1 views

Reactions of rhodium dihydride complexes

Reactions of rhodium dihydride complexes [RhH2(R-DAB)-(PR′3)2]+ with the acetylenes CH3OOCCCCOOCH3 and HCCC6H5. Crystal structure of [RhC(CO2CH3)C(CO2CH3)C(CO2CH3C(CO2CH3)-(C6H11NCHCHNC6H11){PCH3 (C6H5)2} H2O]ClO4

✍ Marta Iglesias; Carmen del Pino; Josep Ros; Severino García Blanco; Sagrario M. 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 842 KB

Assembly of the Transition Metal Substit

Assembly of the Transition Metal Substituted Polyoxometalates ZnW11M(H2O)O3.0.CO;2-X/asset/equation/tex2gif-ueqn-1.gif?v=1&t=h5kuhpte&s=655ae5fcdbff96962b173055e6ca5bb805bed5e7" class="inlineGraphic"> (M=Mn, Cu, Fe, Co, Cr, Ni, Zn) on 4-Aminobenzoic Acid Modified Glassy Carbon Electrode and Their Electrochemical Study

✍ Jianyun Liu; Long Cheng; Shaojun Dong 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 165 KB 👁 1 views

Structural Characterization and Intramol

Structural Characterization and Intramolecular Aliphatic C−H Oxidation Ability of MIII(μ-O)2MIII Complexes of Ni and Co with the Hydrotris(3,5-dialkyl-4-X-pyrazolyl)borate Ligands Tp3.0.CO;2-C/asset/equation/tex2gif-sup-3.gif?v=1&t=h5lp536o&s=a03c9eb1fe277a993afb16d61a4b5e5e1fd6ae14" class="inlineGraphic"> (X=Me, H, Br) and Tp3.0.CO;2-C/asset/equation/tex2gif-sup-4.gif?v=1&t=h5lp536o&s=f62756419e66415fd41eb92c51dc480468265b22" class="inlineGraphic">

✍ Shiro Hikichi; Michito Yoshizawa; Yasuyuki Sasakura; Hidehito Komatsuzaki; Yoshi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 531 KB

The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.