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The Syntheses and Molecular Structure of a Branched Oligosilyl Anion with a Record of Nine Silicon Atoms and of the First Branched Oligosilyl Dianion

✍ Scribed by Yitzhak Apeloig; Gady Korogodsky; Dmitry Bravo-Zhivotovskii; Dieter Bläser; Roland Boese


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
287 KB
Volume
2000
Category
Article
ISSN
1434-1948

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✦ Synopsis


Me 3 Si) 3 Si(Me 2 Si) 2 (Me 3 Si) 2 SiLi (1)
and
LiSi(Me 3 Si) 2 (Me 2 Si) 2-
Si(Me 3 Si) 2 Li (2) were synthesized by the reaction of (Me 3 Si) 3- Si(Me 2 Si) 2 Si(Me 3 Si) 3 in THF with one or two mol-equiva- [a]