Alignment effects in the highly rotating NO X %I vn = 1 fragment generated from photodissociation of CHaONO mr\* at 355 nm have been probed by two-photon laser-induced fluorescence spectra. From polarization experiments the rotational angular momentum of NO fragments was shown to be aligned preferen
The susceptibility anisotropy of CH3CD3 from the second-order rotational Zeeman effect
✍ Scribed by W. Hüttner; H. Häussler; W. Majer
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 366 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The susceptibility anisotropy of ethane was determined to be ~1, -EL= -9.73(65)
x 10S3' cm3 from the Zeeman shift of the J = 0 -1, tiff = 0 rotational transition of C113CD3. The deviation from the bond-tensor additivity scheme is discussed, and the Raylei& depohrisation ratio P = l-77(37) X 10s3, deduced from AC and a pretious Cotton-Mouton effect orientation parameter, is compared with the most recent sattering results.
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A new method for determination of nitrogen chemical shift anisotropies (CSAs) employing 14 N MAS NMR spectroscopy is presented. The method utilizes the effect of the second-order cross-term between the quadrupolar coupling and chemical shift interaction in the average Hamiltonian on the lineshape fo