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The supramolecular structure of the precipitate of acrylonitrile polymers and copolymers

✍ Scribed by N. M. Beder; N. A. Basanova; S. A. Ovsyannikova; G. I. Zaspinok

Publisher
Springer US
Year
1973
Tongue
English
Weight
477 KB
Volume
5
Category
Article
ISSN
0015-0541

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✍ N. Grassie; R. McGuchan πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 English βš– 659 KB

Acidic comonomers exert a strong initiating effect on the exothermic nitrile group oligomerization in polyacrylonitrile. In contrast to the sharp intense transitions for pure homopolymers, the exotherms for the copolymers are very broad with much reduced differential temperatures. This is explained