✍ Scribed by Knut Rurack, Ramon Martinez-Manez
No coin nor oath required. For personal study only.
The combination of supramolecular chemistry, inorganic solids, and nanotechnology has already led to significant advances in many areas such as sensing, controlled motion, and delivery. By making possible an unprecedented tunability of the properties of nanomaterials, these techniques open up whole new areas of application for future supramolecular concepts. The Supramolecular Chemistry of Organic–Inorganic Hybrid Materials gathers current knowledge on the subject and provides an overview of the present state and upcoming challenges in this rapidly growing, highly cross- or interdisciplinary research field.The book details how these designed materials can improve existing materials or generate novel functional features such as chemical amplification, cooperative binding and signal enhancement that are difficult or not at all achievable by classical organic supramolecular chemistry. It also discusses issues related to nanofabrication or nanotechnology such as the directed and controlled assembly or disassembly, biomimetic functions and strategies, and the gating and switching of surface functions or morphology.
The Supramolecular Chemistry of Organic–Inorganic Hybrid Materials......Page 5
Contents......Page 7
Preface......Page 11
Editors and Contributors......Page 15
Abbreviations......Page 21
1. Hybrid (Nano)Materials Meet Supramolecular Chemistry: A Brief Introduction to Basic Terms and Concepts......Page 37
2. Supramolecular Chemistry at the Mesoscale......Page 47
Part One Organic–Inorganic Hybrid Nanomaterials......Page 73
3. Silica-Based Mesoporous Organic–Inorganic Hybrid Materials......Page 75
4. Modified Gold Nanoparticles and Surfaces......Page 149
5. Organically Functionalized Semiconductor Nanocrystals: Synthesis, Properties and System Design for Optoelectronic Applications......Page 191
6. Functionalized Carbon Nanotubes for Bioapplications......Page 233
7. Metal–Organic Frameworks (MOFs) and Coordination Polymers......Page 271
Part Two Improvement of Signaling and Sensing by Organization on Surfaces......Page 307
8. Nanoparticle and Biomolecular–Nanoparticle Hybrid Supramolecular Complexes for Electrochemical Signaling......Page 309
9. Modified Nanoparticles as Nanoelectrocatalysts and Amplifying Sensors......Page 333
10. Signal Generation with Gold Nanoparticles: Photophysical Properties for Sensor and Imaging Applications......Page 355
11. Optical Signaling with Silica Nanoparticles......Page 387
12. Organically Modified Quantum Dots in Chemical and Biochemical Analysis......Page 413
Part Three Control of Supramolecular Nanofabrication, Motion, and Morphology......Page 441
13. Chemically Directed Self-Assembly of Nanoparticle Structures on Surfaces......Page 443
14. Immobilization and Patterning of Biomolecules on Surfaces......Page 469
15. Switchable Host–Guest Chemistry on Surfaces......Page 503
16. Nanogated Mesoporous Silica Materials......Page 515
17. Building Molecular Machines on Surfaces......Page 539
18. Control of Morphology in Mesoporous and Mesostructured Hybrid Materials......Page 567
Part Four Biomimetic Chemistry......Page 583
19. Biomimetically Inspired Signaling......Page 585
20. Imprinted Functionalized Silica......Page 617
21. Bioinspired Block Copolymer-Based Hybrid Materials......Page 635
Part Five Interfacial Chemistry, Multifunctionality, and Interdisciplinarity......Page 673
22. Emerging Concepts in Interfacial Chemistry of Hybrid Materials: Nanocontainer-Based Self-Healing Coatings......Page 675
23. Molecular Schizophrenics: Switchable Materials with Multiple Functions......Page 689
24. Hybrid Nanomaterials Research: Is It Really Interdisciplinary?......Page 709
25. Supramolecular Chemistry Meets Hybrid (Nano)Materials: A Brief Look Ahead......Page 725
Appendix 1......Page 737
Index......Page 743
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